A common, food-safe chemical, methyl benzoate, kills hornworms at all stages, including eggs. From the available, published report, I cannot determine the required concentration. Methyl benzoate does not dissolve well in pure water, but must be diluted in a solvent that is safe to apply to a living leaf. I don't have any definite suggestions for an appropriate solvent, though a touch of dish detergent in water may work well (since methyl benzoate is often used in soaps and shampoos). My suggestion would be to try 1 drop in a pint of solvent (e.g. water with a couple of drops of Dawn dish detergent). Come back later, and see if you can smell the methyl benzoate in this dilution. If not, then add another drop...etc.
Undiluted, methyl benzoate is flammable and toxic. So don't smoke while handling the concentrate, and don't spill it on your skin.
Material Safety Data Sheet: https://www.sciencelab.com/msds.php?msdsId=9927228
For sale:
Bob
Pys.org said:You probably know methyl benzoate when you smell it. The natural compound's wintergreen-spicy, floral-fruity aromas make it a popular ingredient in perfumes, soaps, and shampoos.
...methyl benzoate, a compound approved by the U.S. Food and Drug Administration for use in foods and cosmetics.
...tested methyl benzoate against other agricultural pests, including the brown marmorated stink bug (BMSB), diamondback moth, and tobacco hornworm. He found that the compound can kill all stages of these insects—egg, nymph, and adult—though it works better against smaller insects than larger ones.
https://phys.org/news/2017-06-petunia-shampoo-pesticide.html
Undiluted, methyl benzoate is flammable and toxic. So don't smoke while handling the concentrate, and don't spill it on your skin.
Material Safety Data Sheet: https://www.sciencelab.com/msds.php?msdsId=9927228
For sale:
- ($10 for 30cc) https://www.etsy.com/listing/449482456/methyl-benzoate-30ml
- ($10 for 30cc) http://www.ebay.com/itm/Methyl-Benzoate-30ml-1-fl-oz-/121727334448
Bob